Using JPL Horizons, I found that Earth's aphelion last occurred near the northern winter solstice some time around 9540 BC.
There might be a clever way to get this info from Horizons, but I just used crude estimates and trial & error. This task is a bit tricky. To get accurate results, you need to use the Terrestrial Time (TT) scale; in that epoch, the uncertainty in the difference between Universal Time and TT is rather large.
As I mentioned here, the exact time of Earth's perihelion and aphelion is a little wobbly, mostly because of the influence of the Moon. However, the perihelion and aphelion of the Earth-Moon barycentre (EMB) are more stable, although they do get affected slightly by perturbations from the other planets (I assume Jupiter & maybe Venus are the main culprits). Fortunately, in 9542 BC, the aphelion of the EMB and of the Earth itself are fairly closely aligned.
Here's a graph of the distance from the Sun to the Earth (in blue) and to the EMB (in red). The "+1.525e8" means you need to add 152.5 million km to the numbers on the vertical axis. (For reference, the mean radius of the Earth is 6371 km).
And here's the corresponding graph of the Sun's declination.
Those graphs say that aphelion and solstice occur around midnight on the 5th of March, 9541 BC, or Julian day -1763363.5. Horizons uses the Julian calendar for dates prior to 1582-Oct-15. The equivalent (proleptic) Gregorian calendar date is the 22nd of December, 9542 BC.
FWIW, the aphelion coincided with the June solstice in 1250 AD. It coincided with the March equinox around 4100 BC, and will coincide with the September equinox around 6450 AD.
I just want to say a little more about the variation in the time of perihelion / aphelion. Here's a plot for the year 2000 of the distance from the Sun to the Earth and to the EMB. At this scale, the graphs overlap almost perfectly. That ±~5000 km monthly variation due to the Earth's orbit around the EMB (which you can see in a graph in my linked answer) is pretty small compared to the 5 million km difference between perihelion & aphelion. But as the top graph in this answer shows, we can see the difference if we zoom in close enough.
The year doesn't contain a whole number of synodic months, so the effect of the Earth-EMB orbit on the exact time of Earth's perihelion varies from year to year.
Here's an anim covering the years 2000 to 2019 for 30 days around perihelion. The dots are 1 day apart, but the curves were calculated using 6 hour steps. The frame step is a Julian year of 365.25 days, rather than a calendar year, to (mostly) eliminate the shift due to the leapyear cycle.
The previous version of this anim is https://i.sstatic.net/F86um.gif
The aphelion plot was done using a slightly updated version of the script in this answer: https://space.stackexchange.com/a/58339/38535
The perihelion plot was done using a hacked version of that script. Sorry, but it's a bit too ugly to post. ;)
Here's the Sage / Python Declination script. Please see the Horizons manual for info on the various time formats that Horizons understands.
Here's a converter for Julian day numbers / Gregorian dates / Julian dates. Note that it uses Astronomical years i.e., 1 AD = year 1, 1 BC = year 0, 2 BC = year -1, etc. The code is also available on GitHub.