Why can't neutron stars ignite and explode?

Beyond the Chandrasekhar limit, white dwarfs become extremely hot. As a result, previously unfusable carbon can become fusable, causing nuclear reactions. This leads to a thermal runaway and ultimately a type Ia supernova.

However, this doesn't seem to happen in neutron stars. They can keep gaining mass until they become black holes. After a certain point, shouldn't the immense temperatures cause a thermal runaway like in white dwarfs, leading to their explosion?

If a neutron star gains mass in a gradual way, then the most likely course of events will be that its radius will decrease (that is what happens in objects supported by degenerate matter) until it reaches a General Relativistic instability where its collapse to a black hole is inevitable (when $R$ is somewhere between 1.25 and 2 times the Schwarzschild radius). It is possible that neutrons may transform before that into additional hadronic degrees of freedom or into quark matter, but these are endothermic processes that suck kinetic energy out of the neutron gas and only hasten the collapse.