When you point your 25 cm aperture Newtonian reflector at the Sun you're concentrating sunlight to about 50 watts per square centimeter. About half of that is in IR/UV and will be absorbed in many kinds of optical glass and the rest will be available for imaging, and way too much for it!
If you want to use your full aperture, then you must put a special solar filter over the entrance to your telescope that is designed for this purpose, or find a special filter that can survive at focus.
We generally say that an aperture larger than six inches is not helpful for resolution because of astronomical seeing but this is at night. During the day the turbulence in the atmosphere can be worse and problems can arise even in the air close to the surface heated by the ground. This is why solar telescopes are often located near bodies of water.
So normally it is both dangerous to use a full 10 inch aperture (unless you really really have the correct, safe filters) and unhelpful due to atmospheric turbulence.
However, with plenty of light you have the opportunity for a short exposure time and high frame rate and so even if the transit is fast you may be able to use lucky imaging where one or some of the frames in your rapid photo sequence can be used to make a less-distorted image.
The fastest angular speed that the ISS could have is the orbital velocity divided by the minimum distance. Assuming the orbit is circular (which it nearly is) we can use the vis-viva equation to get
$$v = \sqrt{\frac{GM}{a}}$$
where $GM$ is the Earth's [standard gravitational parameter of 3.986E+14 m^3/2^2 and $a$ is the ISS' semimajor axis which is it's averge altitude (recently) of 400,000 meters plus (by definition) Earth's equatorial radius of 6378137 meters. This gives about 7669 m/s. At a minimum distance of 400,000 meters that's 0.019 radians/second or 1.1 degree per second, or 4 arcseconds in a 1/1000 second exposure.
So if you want to talk about 1 arcsecond resolution you first have to lay hands on a camera with a 1/4000 second shutter speed or faster, or wait for a transit that's closer to the horizon where the angular speed is lower (and the ISS' apparent size is also smaller).
Roughly 100 meters / 400,000 meters is about 50 arcseconds, way bigger than the 1 arcsecond resolution mentioned in the question.
So if you just want to resolve the ISS' shadow's shape against the Sun, you really may not need the full aperture of your telescope.
That means that maybe you can use an off-axis circular aperture covering most of your telescope with only say a 2 or 5 cm hole. This helps cut down on some of the thermal power that can destroy your equipment (or eyes, NEVER, EVER, Not Even A Little look through the telescope or through a camera pointed near the Sun).
Sill, as @planetmaker's answer points out, you will need something big and close like the ISS in order to resolve anything more than a dark dot.
Potentially helpful in Space SE: How does the ISS Transit Finder website get the position of the ISS so accurately?