This question is vague because in physics there is no "MOND takes over". Instead we say that deviations from Newtonian mechanics become large, where "large" depends on our specific problem.
Let's ignore MOND (because the interpolating function - see GrapefruitIsAwesome's answer - is not known) and instead use the relativistic and non-relativistic expressions for kinetic energy. The non-relativistic version is:
$KE = \frac{1}{2} mv^2$
where $m$ is the mass and $v$ is the velocity. The relativistic version is:
$KE = (\gamma-1) mc^2$
where $c$ is the speed of light, $m$ is the rest mass, and $\gamma$ is the Lorentz factor, defined as $\frac{1}{\sqrt{1-v^2/c^2}}$.
Try plotting these two expressions. You end up with something like this (this quick and dirty Excel plot is for $m = 1kg$ and uses $c = 1$; the horizontal axis is $v/c$ and the vertical axis is the kinetic energy).

The orange line is the relativistic kinetic energy, while the blue line is the non-relativistic kinetic energy.
Note that the two "overlap" for small $v$. This is to be expected, because in this regime classical physics is a good approximation. However, the two diverge at larger speeds.
Your question in this context becomes "at what speed does relativistic kinetic energy take over" and there is no answer to it, because there are always deviations between the two expressions once $v > 0$. For example, at $v/c = 0.01$, the non-relativistic equation gives a kinetic energy of 0.00005, while the relativistic equation says it is 0.0000500038. Does this discrepancy matter to you? If for your application the answer is "yes", then this is a speed at which you need to take relativity into account. If "no", then we say relativistic effects are negligible.
If MOND is correct, then Kepler's laws already fail in our solar system. Accordingly, your question is not really answerable.